تخليق بوليمرات موصلة كهربائياً من البولي أثينول / أكاسيد المعادن النانوية للحماية من التأكل والنشاط البكتيري
محتوى المقالة الرئيسي
الملخص
للتأكل اهمية كبيرة للباحث بسبب تأثيره الكبير على سلامة الناس واقتصادهم بشكل مباشر. ولحماية معدن الفولاذ المقاوم للصدأ نوع 304L بأستخدام عملية البلمرة الكهربائية لتخليق بوليمرات موصلة ومن ثم تحسينها بـأستخدام مواد نانوية.تم تخليق بوليمر الانيثول كهربائيا على شكل طبقة طلاء لسبائك الفولاذ المقاوم للصدأ ومن ثم اجراء الفحوصات المختبرية من التشخيص بتقنية الاشعة تحت الحمراء ومطيافية القوة الذرية للبوليمر المحضر لوحده مرة ومع الاكاسيد النانوية مرة اخرى.النتائج بينت تقليل كثافة تيار التأكل بعد تخليق الطلاء على السبيكة مما لو كانت السبيكة لوحدها وان نسبة الحماية قد ارتفعت من 71% للبولي انيثول الى 87% بأستخدام TiO2 والى 98% بأستخدام ZnO. كذلك تم حساب الدوال او المعاملات الحركية والثرموديناميكية (Ea, A, ∆H, ∆S, ∆G ) لعملية التأكل.تضمن البحث دراسة الفعالية البايولوجية للبوليمر المحضر ضد سلالات البكتريا وهي المكورات العنقودية الذهبية والاشريكية القولونية بوجود وعدم وجود المواد النانوية لزيادة كفاءة الطبقة البوليمرية ضد التأكل والبكتريا.
Received 15/01/2023
Revised 27/03/2023
Accepted 29/03/2023
Published Online First 20/09/2023
تفاصيل المقالة
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كيفية الاقتباس
المراجع
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